Synthesis of a phosphorus-containing hybrid porphyrin.

نویسندگان

  • Yoshihiro Matano
  • Takashi Nakabuchi
  • Tooru Miyajima
  • Hiroshi Imahori
  • Haruyuki Nakano
چکیده

A phosphorus-containing hybrid porphyrin was successfully prepared via the BF3-promoted dehydrative condensation between sigma4-phosphatripyrrane and 2,5-bis[hydroxy(phenyl)methyl]thiophene. The NMR and UV-vis absorption spectra, electrochemical measurements, and DFT calculations revealed that the sigma3-P,N2,S-hybrid porphyrin exhibits high aromaticity as an 18pi-electron system in terms of both geometric and magnetic criteria. [structure: see text]

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عنوان ژورنال:
  • Organic letters

دوره 8 25  شماره 

صفحات  -

تاریخ انتشار 2006